In the centrosymmetric title compound, [Cd2(C13H12NOS2)4], pairs of dithiocarbamate ligands exhibit different structural functions.Each of the terminal ligands is bidentately coordinated to one CdII atom and Hockey Protective - Gloves - Intermediate forms a planar four-membered CS2Cd chelate ring, whereas pairs of the tridentate bridging ligands link two neighbouring CdII atoms, forming extended eight-membered C2S4Cd2 tricyclic units whose geometry can be approximated by a chair conformation.The coordination polyhedron of the CdII atoms is a distorted square-pyramid.
The five-membered Tie Downs furan ring and the benzene ring are disordered over two sets of sites with an occupancy ratio of 0.62 (8):0.38 (8).